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Code:
MOF
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Time Slot/Poster Number:
5:30 - 5:50 pm
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Session:
Carbon based materials (nanotubes, graphene, carbon nanostructures)
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On-Chip Rayleigh Imaging and Spectroscopy of Carbon Nanotubes
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| Jiwoong Park
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Cornell University, Ithaca, NY
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| View Abstract PDF |
| Summary |
We report a novel on-chip Rayleigh imaging technique using wide-field laser illumination to measure optical scattering from individual SWNTs on solid substrate with high spatial and spectral resolution. This method in conjunction with calibrated AFM measurements accurately measures resonance energies and diameters for large numbers of SWNTs in parallel. Applying this technique for fast mapping of key SWNT parameters, including electronic-types and chiral indices for individual SWNTs, position and frequency of chirality-changing events, and intertube interactions in both bundled and distant SWNTs. Additionally, we measure uniform resonance optical conductivity near 8e^2/h from different SWNTs based on absolute Rayleigh cross sections.
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Code:
MOF
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Time Slot/Poster Number:
4:00 - 4:30 pm
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Session:
Carbon-Based Materials I
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Raman Spectroscopy of Carbon Nanotubes
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| Federico Villalpando; Gene Dresselhaus; Mildred Dresselhaus
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Massachusetts Institute of Technology, Cambridge, MA
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| View Abstract PDF |
| Summary |
The study of graphene nanostructures has become a frontier area of condensed matter physics, and our focus is directed toward studying double wall carbon nanotubes (DWNTs) and their relation to graphene. Since carbon nanotubes can be either metallic or semiconducting, DWNTs come in four varieties S@S, M@S, S@M and M@M where S@M denotes a semiconducting tube inside a metallic tube. Studies on DWNTs are normally done on ensembles of tubes, so there is no easy way to assess the difference in behavior between the four varieties of DWNTS. For this reason our work focuses on Raman studies of individual DWNTs.
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Code:
MOF
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Time Slot/Poster Number:
5:50 - 6:10 pm
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Session:
Carbon-Based Materials I
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Resonant Raman Spectroscopy of Chirality-Enriched
Semiconducting Single Walled Carbon Nanotubes
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| Juan G. Duque1; Hang Chen2; Svetlana Kilina1; Sergei Tretiak1; Andy Shreve1; Xiaomin Tu3; Ming Zheng3; Anna Swan2; Stephen K. Doorn1
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1Los Alamos National Laboratory, Los Alamos, NM; 2Boston University, Boston, MA; 3National Institute of Standards and Technology, Gaithersburg, MD
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| View Abstract PDF |
| Summary |
We present a Raman spectroscopic investigation of enriched semiconducting samples generated from ion chromatography of DNA-functionalized nanotubes. RBM profiles show very good separation of single chirality semiconducting fractions with very low cross-contamination from other nanotubes. G-band profiles allow testing of different models for the Raman scattering process and reveal new evidence for the importance of non-Condon effects in the Raman response. Investigations into the behavior of the highly dispersive G’ mode enabled us to map the band structure of the different isolated chiralities and to probe variable coupling in the vicinity of the E22 transition.
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